Hydrogen bonded molecular rectangle of N,N¢-bis(3-quinolyl- methylene)diphenylethanedionedihydrazone
By: Patra, K. Goutam
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Contributor(s): Manna, Amit K.
Publisher: New Delhi CSIR 2022Edition: Vol.61(4), Apr.Description: 416-419p.Subject(s): GENERAL CHEMISTRYOnline resources: Click here
In:
Indian journal of chemistry (Section B)Summary: The title compound, N,N¢-bis (3-quinolylmethylene) diphenylethanedionedihydrazone (I) (molecular formula, C34H24N6) has been synthesized by the reaction of quinoline 3-carboxaldehyde and diphenylethanedionedihydrazone in 2:1 molar ratio. The molecular structure has been characterized by room-temperature single-crystal X-ray diffraction which reveals that two quinoline moieties are disposed nearly perpendicularly around the central C-C bond giving an ‘L’ shape to the molecule. This particular geometry gives rise to the hydrogen bonded supramolecular rectangle of two self-complementary molecules. These supramolecular units are further assembled by p-p interaction.
| Item type | Current location | Call number | Status | Date due | Barcode | Item holds |
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Articles Abstract Database
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School of Pharmacy Archieval Section | Not for loan | 2023-0728 |
The title compound, N,N¢-bis (3-quinolylmethylene) diphenylethanedionedihydrazone (I) (molecular formula, C34H24N6) has been synthesized by the reaction of quinoline 3-carboxaldehyde and diphenylethanedionedihydrazone in 2:1 molar ratio. The molecular structure has been characterized by room-temperature single-crystal X-ray diffraction which reveals that two quinoline moieties are disposed nearly perpendicularly around the central C-C bond giving an ‘L’ shape to the molecule. This particular geometry gives rise to the hydrogen bonded supramolecular rectangle of two self-complementary molecules. These supramolecular units are further assembled by p-p interaction.
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